Product ID:G2 AEROSOL SPRAY LINE-2 (PAINTS), G2C159 GRAVEL GUARD
MSDS Date:08/01/1992
FSC:8010
NIIN:00N070932
MSDS Number: BZSSP

SHERWIN-WILLIAMS CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

760

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 15%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: 15%

OSHA PEL N/K

ACGIH TLV: N/K

22

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 15%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

180

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 30%

OSHA PEL 1000 PPM

ACGIH TLV: 750PPM/1000STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 20%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

OVEREXP TO SOLV W/PERM BRAIN & NERV SYS

RTECS: 9999999ZZ

OTHER SOLV. TOLUENE APPEARS ON NAVY LIST OF OCCUP

RTECS: 9999999ZZ

PROFESSIONALS CONCERNING LATEST HAZARD LIST

RTECS: 9999999ZZ

INCINERATE. DEPRESSURIZE CONTAINER.

RTECS: 9999999ZZ

PILOT LIGHTS & HEATERS. TURN OFF STOVES, ELEC

RTECS: 9999999ZZ

CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING

RTECS: 9999999ZZ

EXPOSE TO TEMPS > 120F. HEAT FROM SUNLIGHT,

RTECS: 9999999ZZ

CAUSE CONTR TO BURST. DO NOT TAKE INTERNALLY. KEEP

RTECS: 9999999ZZ

DELIBERATELY CONCENTRATING AND INHALING THE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TO MIN EXPOS, FOLLOW REC FOR PROPER
USE, VENT & PERS PROT EQUIP. ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & L OSS OF COORD INDICATE EXCESS EXPOS
TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: EYE/EXCESS SKIN EXPOS. CHRONIC: PRLNG
EXPOS TO SOLV MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD
FORMING, CARDIO-VASCULAR & REPRO SYS. RATS EXPOSED TO TITANIUM
DIOXIDE DUST AT 250 MG/M3 D EVELOPED LUNG CANCER, HOWEVER, SUCH
EXPOS LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD
& PRLNG (ING 6)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: IF ANY BRTHG PROBLEMS OCCUR DURING USE, LEAVE AREA &
GET FRESH AIR. IF PROBLEMS REMAIN/OCCUR LATER, IMMED GET MED ATTN.
SKIN: WASH AFFECTED AREA THORO W/SOAP & WATER. REMOVE CONTAM CLTHG
& LAUN DER BEFORE REUSE. EYES: FLUSH W/LGE AMTS OF WATER FOR AT
LEAST 15 MIN. GET MED ATTN. INGEST: GET MED ATTN.

Flash Point:<21F,<-6C
Lower Limits:0.5%
Upper Limits:12.0%
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZ ARE
PREF. WATER MAY BE USED TO COOL (SUP DAT)
Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATION TO HOT (SUP DAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:THIS COATING MAY CONTAIN MATLS
CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ
LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM.
Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP/SPRAY MIST.
AVOID CONT W/SKIN & EYES. CONTENTS EXTREMELY FLAM. KEEP AWAY FROM
HEAT, SPARKS & OPEN FLAME. DURING USE & UNTIL ALL VAPS ARE GONE,
KEEP AREA VENT. DO NOT SMOKE. EXTING ALL FLAMES, (ING 10)

Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED < APPLIC LIM
BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY
NIOSH/MSHA FOR PROT. WHEN SANDING, WIREBRUSHING, ABRADING,
BURNING/WELDING DRIED FILM, WEAR NIOSH/MSHA APPRVD PARTICULATE
RESP.
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
< APPLIC EXPOS LIM. REFER TO OSHA STDS 1910.94, (SUP DAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
EXTING MEDIA: CLSD CONTRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO
WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURF REQUIRES SPEC PREC.
DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ.
SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. VENT: 1910.107,
1910.108.

Boiling Pt:B.P. Text:<395F,<202C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:>75

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE #. WASTE FROM PRODS CONTAINING METHYL ETHYL
KETONE MAY ALSO RE QUIRE TESTING FOR EXTRACTABILITY. DO NOT (ING 9)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.